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The synthesis of four new bis(amino-p-chlorophenylglyoximes) and their polymeric complexes

Access

info:eu-repo/semantics/closedAccess

Date

1997

Author

Pekacar, AI
Mercimek, B
Ozcan, E

Metadata

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Abstract

In this study, four new bis(amino-p-chlorophenylglyoximes), 1,2-phenylenebis(amino-p-chlorophenylglyoxime) L(1)H(2), 1,5-naphthylenebis(amino-p-chlorophenylglyoxime) L(2)H(2), 3,4-tolylenebis(amino-p-chlorophenylglyoxime) L(3)H(2), and 2,6-pyridylbis(amino-p-chlorophlenylglyoxime) L(4)H(2), have been synthesized from anti-p-chlorophenylchloroglyoxime and the corresponding aromatic diamines. Their polymeric complexes with Ni(II), Co(II) and Cu(II) have been prepered. The Ni(II) and Cu(II) complexes of these ligands have been found to be square-planar, while the Co(II) complexes are octahedral with water molecules as axial ligands. H-1 NMR, AAS, IR, magnetic susceptibility and elemental analytical data of the complexes and ligands are discussed.

Source

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY

Volume

27

Issue

3

URI

https://dx.doi.org/10.1080/00945719708000201
https://hdl.handle.net/11480/5836

Collections

  • Makale Koleksiyonu [2055]
  • Öksüz Yayınlar Koleksiyonu - Scopus [2338]
  • Öksüz Yayınlar Koleksiyonu - WoS [2361]



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